Effects of crystal structure on the activity of MnO 2 nanorods oxidase mimics
Nano Research(2020)
摘要
The crystal structures would directly affect the physical and chemical properties of the surface of the material, and would thus influence the catalytic activity of the material. α-MnO 2 , β-MnO 2 and γ-MnO 2 nanorods with the same morphology yet different crystal structures were prepared and tested as oxidase mimics using 3,3’,5,5’-tetramethylbenzidine (TMB) as the substrate. β-MnO 2 that exhibited the highest activity had a catalytic constant of 83.75 μmol·m −2 ·s −1 , 2.7 and 19.0 times of those of α-MnO 2 and γ-MnO 2 (30.91 and 4.41 μmol·m −2 ·s −1 ), respectively. The characterization results showed that there were more surface hydroxyls as well as more Mn 4+ on the surface of the β-MnO 2 nanorods. The surface hydroxyls were conducive to the oxidation reaction, while Mn 4+ was conducive to the regeneration of surface hydroxyls. The synergistic effect of the two factors significantly improved the activity of β-MnO 2 oxidase mimic. Using β-MnO 2 , a β-MnO 2 -TMB-GSH system was established to detect the content of glutathione (GSH) rapidly and sensitively by colorimetry. This method had a wide detection range (0.11-45 μM) and a low detection limit (0.1 μM), and had been successfully applied to GSH quantification in human serum samples.
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关键词
crystal phase structure, MnO2
, oxidase mimics, surface hydroxyls, 3,3’,5,5’-tetramethylbenzidine (TMB), glutathione
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