Salt-Templated Platinum-Copper Porous Macrobeams for Ethanol Oxidation

Platinum nanomaterials provide an excellent catalytic activity for diverse applications and given its high cost, platinum alloys and bi-metallic nanomaterials with transition metals are appealing for low cost and catalytic specificity. Here the synthesis of hierarchically porous Pt-Cu macrobeams and macrotubes templated from Magnus's salt derivative needles is demonstrated. The metal composition was controlled through the combination of [PtCl4](2-) with [Pt(NH3)(4)](2+) and [Cu(NH3)(4)](2+) ions in different ratios to form salt needle templates. Polycrystalline Pt-Cu porous macrotubes and macrobeams 10' s-100' s mu m long with square cross-sections were formed through chemical reduction with dimethylamine borane (DMAB) and NaBH4, respectively. Specific capacitance as high as 20.7 F/g was demonstrated with cyclic voltammetry. For macrotubes and macrobeams synthesized from Pt2-:Pt2+:Cu2+ salt ratios of 1:1:0, 2:1:1, 3:1:2, and 1:0:1, DMAB reduced 3:1:2 macrotubes demonstrated the highest ethanol oxidation peak currents of 12.0 A/g at 0.5 mV/s and is attributed to the combination of a highly porous structure and platinum enriched surface. Salt templates with electrochemical reduction are suggested as a rapid, scalable, and tunable platform to achieve a wide range of 3-dimensional porous metal, alloy, and multi-metallic nanomaterials for catalysis, sensor, and energy storage applications.