Negative Fermi-level Pinning Effect of Metal/n-GaAs(001) Junction Induced by Graphene Interlayer.

It is demonstrated that the electric dipole layer due to the overlapping of electron wavefunctions at metal/graphene contact results in negative Fermi-level pinning effect on the region of GaAs surface with low interface-trap density in metal/graphene/n-GaAs(001) junction. The graphene interlayer takes a role of diffusion barrier preventing the atomic intermixing at interface and preserving the low interface-trap density region. The negative Fermi-level pinning effect is supported by the Schottky barrier decreasing as metal work-function increasing. Our work shows that the graphene interlayer can invert the effective work-function of metal between and , making it possible to form both Schottky and Ohmic-like contacts with identical (particularly work-function) metal electrodes on a semiconductor substrate possessing low surface-state density.