Isotropic Charge Screening Of Anisotropic Black Phosphorus Revealed By Potassium Adatoms

Black phosphorus has attracted great research interest due to its numerous applications in electronic devices, optoelectronic devices, energy storage, and so on. Compared with the majority of two-dimensional materials, black phosphorus possesses a unique property-its strong in-plane anisotropy. All the properties reported so far, including its effective mass, electron mobility, light absorption, thermal conductivity, and so on, have shown great anisotropy in the basal plane. This property renders black phosphorus applications not achievable with other two-dimensional materials. In this work, however, we discover a remarkable isotropic behavior in the strongly anisotropic black phosphorus-its electrostatic screening of point charges. We use the tip-induced band bending of a scanning tunneling microscope to map out the Coulomb field of ionized potassium adatoms on black phosphorus and reveal its isotropic charge screening. This discovery is important for understanding electron scattering and transport in black phosphorus.