Selection Rules For Nonradiative Carrier Relaxation Processes In Semiconductor Quantum Dots

Time-resolved intensity cross-correlation measurements of radiative cascades are used for studying nonradiative relaxation processes of excited carriers confined in semiconductor quantum dots. We spectrally identify indirect radiative cascades which include intermediate phonon-assisted relaxations. The energy of the first photon reveals the multicarrier configuration prior to the nonradiative relaxation, while the energy of the second photon reveals the configuration after the relaxation. The intensity cross-correlation measurements thus provide quantitative measures of the nonradiative processes and their selection rules. We construct a model which accurately describes the experimental observations in terms of the electron-phonon and electron-hole exchange interactions. Our measurements and model provide a tool for engineering relaxation processes in semiconductor nanostructures.