Separately enhanced dual emissions of the amphiphilic derivative of 2-(2'-hydroxylphenyl) benzothiazole by supramolecular complexation.

Here, we report separately enhanced dual emissions of the amphiphilic derivative of 2-(2-hydroxyphenyl)benzothiazole (denoted as HBT-11) by supramolecular complexation with cyclodextrins (CDs). When dispersed in water, HBT-11 shows two relatively weak emission bands, which can be assigned to the emissions of enol- and keto-forms, the two tautomers, owing to excited-state intramolecular proton transfers. Upon the addition of -CD and -CD, the keto- and enol-emissions, respectively, are separately enhanced; the enhancement effect is due to the formation of HBT-11/-CD and HBT-11/-CD complexes through multiple hydrogen bonding and host-guest interactions, respectively. It is worth to note that the keto-emission caused by the complex of HBT-11/-CD has a much shorter wavelength compared with that of the aggregates formed by pure HBT-11. To the best of our knowledge, this is the first time that a study on keto-emission of the isolated HBT chromophore has been reported.