A Novel Type of Battery-Supercapacitor Hybrid Device with Highly Switchable Dual Performances Based on a Carbon Skeleton/Mg 2 Ni Free-Standing Hydrogen Storage Electrode.

The sharp proliferation of high power electronics and electrical vehicles has promoted growing demands for power sources with simultaneous performances of high energy and power densities. Under the circumstances, battery-supercapacitor hybrid devices are attracting considerable attention as they combine the advantages of both batteries and supercapacitors. Here, a novel type of hybrid device based on carbon skeleton / Mg2Ni free-standing electrode without the traditional nickel foam current collector is reported, which has been designed and fabricated through a dispersing-freeze drying method by employing the reduced graphene oxide (rGO) and multi-walled carbon nanotubes (MWCNTs) as hybrid skeleton. As a result, the Mg2Ni alloy is able to deliver a high discharge capacity of 644 mAh g-1 and more importantly, a high cycling stability with retention over 78% after 50 charge/discharge cycles has been achieved, which exceeds almost all the results ever reported on Mg2Ni alloy. Simultaneously, the electrode could also exhibit excellent supercapacitor performances including high specific capacities (296 F g-1) and outstanding cycling stability (100% retention after 100 cycles). Moreover, the hybrid device can switch between battery and supercapacitor modes immediately for need during application. These features make the C skeleton/alloy electrode a highly promising candidate for battery-supercapacitor hybrid devices with high power/energy density and favorable cycling stability.