The supramolecular effect of stilbenophanes on the Wacker oxidation progress: A structure–activity relationship study
Journal of Organometallic Chemistry(2015)
摘要
The Wacker oxidation of cis and trans isomers of two defined stilbenophanes with different alkyl chain lengths gave the corresponding cyclic ketones in different rate. It was found that the oxidation rate of stilbenophanes is in order to: E-1 >> Z-3 ∼ Z-1 > E-3 to show the importance of supramolecular effect of trans isomers in elucidation of the reaction mechanism. Cyclic voltammetry and Uv–Vis measurements showed a different behavior for the complexation of trans isomers with palladium ion to confirm the Wacker oxidation data.
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关键词
The Wacker oxidation,Stilbenophanes,Structure–activity relationship
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