An Isothermal Model for Predicting Performance Loss in PEMFCs from Balance of Plant Leachates

A model is presented for the contamination of a proton exchange membrane fuel cell (PEMFC), including adsorption onto the Pt catalyst, absorption into the membrane, and ion exchange with ionomeric components. Model predictions for three sources of voltage loss account for the two-dimensional, time-dependent contamination along the channel and into the membrane. The model is developed by considering the well-known concepts of Langmuir adsorption, partition coefficients, plug flow reactors (PFRs), and dimensionless analysis. The phenomena are shown to be controlled by three important dimensionless groups: a Damkohler number for the contamination reaction rate, a capacity ratio, and a coverage ratio for each contamination mechanism. These groups show how to scale ex situ equilibrium data for in situ predictions. The model predictions are shown to be reasonable when compared to in situ experiment data once ex situ data are used to provide reaction and equilibrium parameters. The predictions enable estimation of tolerance limits for leachates according to each mechanism. For typical parameters, the predicted voltage loss in the electrode ionomer by an ion-exchange mechanism shows slower reaction rates but greater performance losses than other mechanisms. (C) The Author(s) 2014. Published by ECS. All rights reserved.