The first stereoselective total synthesis of the Z-isomer of (6S,7R,9R)-6,7-dihydroxy-9-propylnon-4-eno-9-lactone

Palakodety Radha Krishna,Sunchu Prabhakar,Kallaganti V S Rama Krishna

RSC ADVANCES（2013）

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摘要

The first stereoselective total synthesis of the Z-isomer of (6S,7R,9R)-6,7-dihydroxy-9-propylnon-4-eno-9-lactone involving Sharpless titanium(IV) mediated regioselective ring-opening reaction, Steglich esterification and RCM as the key steps is reported.

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