Nanolithography For 3-Dimentional Nanostructures: Enhancement Of Light Output Power In Vertical Light Emitting Diodes

GALLIUM NITRIDE MATERIALS AND DEVICES VIII(2013)

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摘要
We review the recent developments to enhance the external quantum efficiency (EQE) in GaN based vertical light-emitting diodes (V-LEDs). The controlling of side-wall angle by SiO2 nanosphere lithography significantly improved the light extraction efficiency (LEE) of V-LEDs; this result is 6% higher than the photo chemical etching (PCE) method, which is known to have the highest light extraction, and 300% higher than flat surface V-LEDs. Nanostructured V-LEDs with a very dense forest of vertically aligned ZnO nanowires on the surface of N-face n-GaN induce the dramtic improvement in LEE. The structural transformation at the nanolevel by the UV radiation and Ozone (UV-O) treatment contributes the high density of Zn seed on GaN, and then this approach shows an extreme enhancement in LEE (>2.8x) compared to flat V-LEDs. The enhanced LEE was also demonstrated by depositing a spontaneously formed MgO nanopyramids and ZnO refractive-index modulation layer on the surface of V-LEDs, resulting in the increase of output power by 49 %, comparing with the V-LEDs with a flat n-GaN surface. The enhancement of light output power by the nanotexturing of n-face n-GaN was remarkably influenced by 3-dimentional nanostructures.
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关键词
vertical light-emitting diodes, Total internal reflection, Nanosphere lithography, ZnO nanorod, photochemical etching, MgO nano-pyramids
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