Sources For Cadmium Diffusion In Inp Kinetics In Short Duration Anneals

Short duration cadmium diffusion in sealed ampoules was studied at a temperature of 550 degrees C and a Cd/P molar ratio of 0.28. The starting sources were physical mixtures of either elemental Cd metal and red P or Cd3P2 and red P. The Cd profiles were determined by SIMS In relatively short diffusion anneals up to two hours, the surface concentration, or solubility of Cd with either diffusion source is the same. However, Cd penetration was shallower in samples diffused with elemental (Cd, P) mixture than in samples diffused with (Cd3P2, P) mixture as the starting source. The slower diffusion of Cd with elemental starting source (Cd, P) appears to be related to the kinetics involved in reaching the thermal equilibrium between CdP2 and CdP4.. The formation of Cd3P2 en route to the eventual formation of CdP2 and CdP4 or surface related kinetics are proposed as plausible mechanisms. The results appear to be consistent with the establishment of thermal equilibrium between CdP2 and CdP4 at a Cd/P ratio of 0.28 per the available phase equilibria data. The diffusion kinetics and defect structure are discussed on the basis of quasi-equilibrium among the three condensed phases InP, CdP2 and CdP4.