Enantiospecific total synthesis of (-)-bengamide E.

Prashant K Metri,Raphael Schiess,Kavirayani R Prasad

CHEMISTRY-AN ASIAN JOURNAL（2013）

引用 17|浏览6

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摘要

Total synthesis of the polyhydroxy caprolactam amide natural product, bengamide E, is accomplished starting from tartaric acid. Key reactions in the synthesis include desymmetrization of the bis(dimethylamide) unit of tartaric acid, Zn(BH4)2-mediated anti-selective reduction, and a HornerWadsworthEmmons olefination.

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关键词

anti-cancer compounds,metathesis,natural products,polyhydroxy compounds,total synthesis

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