Surface resistivity modification of polyimide film by plasma source ion implantation

Plasma Science(2011)

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摘要
Summary form only given. Plasma source ion implantation (PSII) is a very useful technique in modifying characteristics of the material surfaces. We used a modified PSII process in which repetitive high voltage pulses were applied to grids placed far outside of the sheath region. It was formed at the surface of the polyimide immersed in the plasma. The mechanism of the ion acceleration in the modified PSII system was investigated by the simulation using the XOOPIC program. After the surface treatment using the modified PSII process with the inductive coupled plasma, the surface resistivity of polyimide was decreased from 1016 ohm/square to the range of 106 ~ 109 ohm/square. Polyimide was modified to improve the surface electrical conductivity in the energy range of 5 ~ 30 kV. The TEM analysis showed that the MPSII treatment with -30 kV pulse changed the structure of the polyimide to a depth of 90 nm. We present the modified PSII system and the surface resistivity dependency by the pulse shape and treatment time.
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关键词
electrical conductivity,electrical resistivity,physics computing,plasma immersion ion implantation,plasma sheaths,plasma simulation,polymer films,solid-state phase transformations,surface treatment,transmission electron microscopy,tem,xoopic program,depth 90 nm,inductive coupled plasma,ion acceleration,plasma source ion implantation,polyimide film,pulse shape,repetitive high voltage pulses,sheath region,structural change,surface electrical conductivity,surface resistivity modification,treatment time,voltage -30 kv,ion implantation
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