A high-strength SiC w /SiC–Si composite derived from pyrolyzed rice husks by liquid silicon infiltration

Journal of Materials Science(2012)

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摘要
A high-strength SiC composite with SiC whiskers (SiC w ) as reinforcement has been fabricated by liquid silicon infiltration (LSI) using pyrolyzed rice husks (RHs) as raw material. RHs were coked and pyrolyzed subsequently at high temperature to obtain a mixture containing SiC whiskers, particles, and amorphous carbon. The pyrolyzed RHs were then milled and modeled to preforms, which were then used to fabricate biomorphic SiC w /SiC–Si composites by liquid silicon infiltration at 1,450, 1,550, and 1,600 °C, respectively. Dense composite with a density of 3.0 g cm −3 was obtained at the infiltration temperature of 1,550 °C, which possesses superior mechanical properties compared with commercial reaction-sintered SiC (RS-SiC). The Vickers hardness, flexure strength, elastic modulus, and fracture toughness of the biomorphic SiC w /SiC–Si composite were 18.8 ± 0.6 GPa, 354 ± 2 GPa, 450 ± 40 MPa, and 3.5 ± 0.3 MPa m 1/2 , respectively. Whereas the composites obtained at the other two infiltration temperatures contain unreacted carbon and show lower mechanical properties. The high flexure strength of the biomorphic composite infiltrated at 1,550 °C is attributed to the dense structure and the reinforcement of the SiC whiskers. In addition, the fracture mechanism of the composite is also discussed.
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关键词
Fracture Toughness,Vickers Hardness,Weibull Modulus,Flexure Strength,Chemical Vapor Infiltration
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