Ferrocene Mono- and Di-Sulfonates as Building Blocks in Hydrogen-Bonded Networks

Jingli Xie,Brendan F. Abrahams,Tobias J. Zimmermann,Arindam Mukherjee,Anthony G. Wedd

AUSTRALIAN JOURNAL OF CHEMISTRY（2007）

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摘要

The structure directing influence of a variety of hydrogen-bonding cations on the arrangement of ferrocene mono-and di-sulfonate anions within the crystalline state is reported. The crystal structures of four different networks of composition A[Fe(eta(5)-C5H5)(eta(5)-C5H4SO3)] (A= imidazolium or N-methylimidazolium) and B-2[Fe(eta(5)-C5H4SO3) 2] (B= imidazolium or pyridinium) are presented. The imidazolium ions are able to act as hydrogen bond bridges in the generation of layer-type structures similar to those found for guanidinium analogues. Secondary bonding interactions exert a powerful structure-directing influence within these networks even though the individual interactions appear to be rather weak.

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关键词

density functional theory,medicinal chemistry,mass spectrometry,biosensors,catalysis,photochemistry,kinetics,spectroscopy,self assembly,peptide,biocatalysis,interfaces,green chemistry,surface chemistry,hydrogen bond,combinatorial chemistry,supramolecular chemistry,crystal structures,inorganic chemistry,amino acids,reaction mechanisms,ab initio calculations,crystallography,quantum chemistry,macromolecules,pharmaceutical chemistry,structure,proteins,electrochemistry,physical chemistry,ionic liquids,enzymes,colloids,computational chemistry,polymer chemistry,sensors,combinatorial,nanotechnology,organic chemistry,biological chemistry,analytical chemistry,educational

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