Asphaltene Self-Association and Precipitation in Solvents—AC Conductivity Measurements
msra(2007)
摘要
Techniques used for investigating asphaltene self-association are reviewed. The principles, fundamental differences, and limits
of each technique are briefly discussed. A new approach using AC conductivity measurement for detecting asphaltene self-association
is proposed and demonstrated using Alberta bitumenderived asphaltene as a model system. Preliminary results showthat the ACconductivity
measurement is sensitive to subtle capacitance change arising from asphaltene self-association but only within a certain frequency
range. Apercolation model with parallel capacitor–resistor circuit is adopted to establish the theoretical basis for this
approach. This model predicts the functional behavior of the AC conductivity and exhibits phase transition-like behavior upon
asphaltene self-association. The conductivity measurements show functional forms similar to the predicted ones and exhibit
discontinuity near 120 mg/L in toluene where self-association is believed to occur. This value agrees (on the same order of
magnitude) with earlier surface tension,1 laser thermal lensing,2 and ultrasonic3 measurements. In addition to detecting asphaltene self-association, AC conductivity is also applicable to characterization
of asphaltene precipitation in toluene upon addition of nonsolvent such as heptane. The sensitivity is high and the method
is simple. These two experiments suggest that AC conductivity method can be a good option for measuring flocculation, precipitation,
and phase separation of petroleum complex fluids, provided the right frequency range is chosen. Further validation of this
method is needed for other complex fluids.
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