Performance analysis of non-isothermal solar reactors for methanol decomposition

A procedure for analyzing the performance of non-isothermal solar reactors for methanol decomposition was developed, based on a model of thermal loss from direct steam generation collector and a comprehensive kinetic model of methanol decomposition employing BASF K3-110 catalyst. It was found that catalytic bed temperature tends towards a certain value, which depends on the chemical reaction type, radiation intensity and collector structure mainly. For a beam incidence angle of 0°, system efficiency increases from 56% at a radiation intensity of 400Wm−2 to almost 58% at a radiation intensity of 1000Wm−2. For a radiation intensity of 400Wm−2, beam incidence angle of 20°, absorber length of 10m, feed temperature of 373K and ratio of reaction section of 0.9, the mole flow rate of feed in the range of 0.21–0.23mols−1 results in a maximum quantity of reacted methanol of 0.146mols−1, while a mole flow rate of feed of 0.15mols−1 leads to a maximum system efficiency of 54.2%. The research indicates that the pre-heating section should be as short as possible for effective use of solar energy.