Temporal variability of atmospheric columnar CO2, CH4, CO and N2O concentrations using ground-based remote sensing FTIR Spectrometer

Solar absorption spectra collected using a ground-based Fourier Transform Infrared (FTIR) Spectrometer were used to retrieve the column-averaged concentrations (X) of CO2, CH4, CO, and N2O during the years 2016–2019 in the Suburban region of Shadnagar, Telangana, India. For the research period, the diurnal mean amplitudes of XCO2, XCH4, XCO, and XN2O are ∼ 13 ppmv, ∼50 ppbv, ∼13 ppbv, and ∼ 19 ppbv respectively. Strong seasonality at the study site is indicated by the seasonal variations of XCO2 and XCO of 18.3 ppmv and 39.2 ppbv, respectively. Additionally, we compared FTIR data to XCO2 detected by Orbiting Carbon Observatory-2 (OCO-2) and CO columns from Measurements of Pollution in the Troposphere (MOPITT). For the XCO2 and CO columns, the comparison research shows a mean relative bias between FTIR data and satellite data of 0.92 % and 0.71 %, respectively. The FTIR and satellite data show a Pearson correlation coefficient (r) of 0.71 (XCO2, N = 26 co-located) and 0.60 (CO columns, N = 44), respectively. The findings demonstrate a good agreement between our data and satellite data.