Vertically grown MoS2 nanosheets on graphene with defect-rich structure for efficient sodium storage

The synthesis of a perpendicular growth structure of MoS2 nanosheets on graphene for efficient sodium storage is challenging yet ideal due to the benefits of open ion diffusion channels and high electronic conductivity. In this study, we have successfully fabricated a novel structure of vertical MoS2 nanosheets on graphene, with ZnS nanoparticles serving as bonding points (MoS2/ZnS/G), through a facile hydrothermal method. During the synthesis process, Zn2+ not only acts as a landing site for the vertical growth of MoS2 nanosheets but also triggers the formation of a defect-rich structure in the final samples. This unique architecture of MoS2/ZnS/G effectively combines the advantages of a vertically aligned geometry and a defect-rich structure for energy storage. The resulting structure displays shortened transport paths for electrons/ions, enhanced conductivity, improved structural integrity, and an increased number of active sites for promising electrochemical performance. As expected, when used as anode for sodium-ion batteries, the as-synthesized MoS2/ZnS/G exhibits excellent rate capability (high capacity of 298 mAh·g−1 at 5 A·g−1) and good cycling stability (a capacity decay of 0.056