Experimental Modeling of the Mantle-Slab Interaction in the Metal-Carbonate System, Conditions of Crystallization and Indicator Characteristics of Diamond

studies aimed at determining the conditions for the formation of diamond and graphite as a result of the redox interaction of reduced mantle rocks and oxidized rocks of the slab in a wide temperature range, including the conditions of both "cold" and "hot" subduction, were carried out on a "split-sphere" multianvil high-pressure apparatus (BARS) in the (Fe,Ni)-(Mg,Ca)CO3 sys-tem, at 6.3 GPa and 800-1550 & DEG;C for 35-105 h, using the "sandwich" assembly. We have established that the interaction of Fe,Ni metal and carbonate is due to the creation and propagation of a redox front, at rates from 1.3 (800 & DEG;C) to 118 & mu;m/h (1550 & DEG;C). At T < 1200 & DEG;C, this interaction leads to the formation of alternating reaction zones (from the reduced center to the oxidized periphery): metal & RARR; metal + wustite/magnesiowustite & RARR; magnesiowustite + graphite & PLUSMN; Mg,Fe,Ca carbonates & RARR; magnesite + aragonite. In this case, in the reduced part of the samples, the formation of a Ni,Fe metal phase strongly enriched in Ni (up to 65-70 wt.% vs. the initial 10 wt.%) was recorded. At higher temperatures, the formation of Fe,Ni metal-carbon (>1200 & DEG;C) and carbonate (>1330 & DEG;C) melts was observed. We have found that the presence of nickel precludes the formation of carbides in the reduced part of the sample and ensures stable diamond crystallization at 1400-1550 & DEG;C both in metal-carbon and carbonate melts. Our experiments demonstrate that diamonds from the metal-carbon melt are characterized by inclusions of taenite and magnesiowustite. The morphology of these diamonds is determined by the {111} layer-by-layer grown faces, and their indicator characteristics are nitrogen-vacancy and nickel-related (884 nm) centers at 1400 & DEG;C or nickel-nitrogen centers (S3, 598 nm, 727 nm, 746 nm, etc.) at 1550 & DEG;C. For diamonds formed in the carbonate melt, the morphology is determined by the {100} and {111} (vicinal-growth) faces; carbonates are identified as inclusions; and nitrogen-vacancy centers H3, NV0, and NV- are fixed in the photoluminescence spectra. Experiments show that the indicator of the metal-carbonate interaction temperature is the degree of structural perfection of graphite, which increases in the range of 800-1550 & DEG;C.