Luminescence enhanced temperature sensor based on the up-conversion emission in Er3+/Yb3+/Mo6+tri-doped tellurite fiber*

CERAMICS INTERNATIONAL(2023)

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摘要
In this study, the green up-conversion (UC) fluorescence emission in Er3+/Yb3+/Mo6+ tri-doped tellurite glasses (TeO2-ZnO-Li2CO3-Bi2O3, TZLB) was explored for temperature sensing. The doping of Mo6+ ions allowed enhanced luminescence at moderate power pumping, avoiding the introduction of undesired laser-induced thermal effects while improving the spectral signal-to-noise ratio. The luminescence characteristics were investigated in detail at different doping molar ratio of Mo6+ ions, and the strongest was observed at 8 mol%. Drawing on tri-doped TZLB glass with the strongest UC emission intensity, a tri-doped TZLB fiber was fabricated and coupled with two multimode fibers (MMFs) via Ultraviolet (UV) adhesive, forming the temperature sensor. The sensor was further encapsulated by a silica tube sealed with Ultraviolet adhesive, overcoming the poor mechanical property of tellurite fiber. The temperature information could be demodulated based on the fluo-rescence intensity ratio technique. The temperature sensing performance of the tri-doped TZLB sensor was investigated as temperature varied from 258 to 420 K and its repeatability was experimentally verified. The Er3+/Yb3+/Mo6+ tri-doped TZLB has an application prospect in the field of lighting, and the so-based temper-ature sensor is expected to be applied to thermal detection in the fields of medical diagnostics, environmental monitoring, and optical thermometers, etc.
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关键词
Up -conversion fluorescence emission, Enhanced luminescence, Tri-doped TZLB fiber, Fluorescence intensity ratio
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