Electronic Distribution Tuning of Vanadium-Cobalt Bimetallic Mofs for Highly Efficient Hydrazine-Assisted Energy-Saving Hydrogen Production

Substituting oxygen evolution reaction (OER) by hydrazine oxidation reaction (HzOR) is a very efficient energy-saving strategy for water electrolysis. Therefore, exploring low-cost and efficient catalysts for HzOR and hydrogen evolution reaction (HER) is very significant to address the great challenge for hydrogen production. Herein, a series of vanadium-cobalt bimetal-organic frameworks [Vx-Co-MOFs: x represents the mass fraction of V element: V/(V+Co)] are synthesized through a one-pot hydrothermal method. The V41.7wt%-Co-MOF exhibits excellent multifunctional catalytic activity. The overall hydrazine splitting (OHzS) delivers 10 mA cm−2 at an ultralow cell voltage of 0.21 V. The superior performance can be ascribed to that the presence of cobalt-vanadium bimetals, which leads to the lattice disorder, an increase in specific surface area and mesoporous structure in V41.7wt%-Co-MOF, thus ensuring the exposure of more active sites. Particularly, the in-situ Raman test indicates that V41.7wt%-Co-MOF is partially converted into Co(OH)2 in the process of electrolysis to form a heterostructure. DFT calculations further show the charge transfer between Co and V, along with the good synergy between V-Co-MOF and Co(OH)2 improves the HER and HzOR performance of V41.7wt%-Co-MOF. This study provides a promising Co-V based catalyst for energy saving hydrogen production.