Snse Nanoplates Swallowed in Carbon Nanofibers as the Self-Standing Anode for Lithium-Ion and Sodium Batteries with Enhanced Performance

Social Science Research Network(2022)

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摘要
SnSe is a promising anode candidate for both lithium-ion and sodium batteries (LIBs and SIBs) with high theoretic capacities, low toxicity and abundant resources. However, it suffers a short cycling life due to the poor conductivity and volume expansion when used as anode material. To improve its Li/Na storage properties, SnSe nanoplates are encapsulated in carbon nanofibers formation a 3D conductive network via a moderate electrostatic spinning and heat treatment. The modified SnSe anode exhibits textile-like feature with extensively mechanical flexibility, and was directly used as anode without and additives for both LIBs and SIBs. It delivers an excellent cycle performance with a high capacity (598 mA h g−1 after 400 cycles for LIBs and 240 mA h g−1 after 250 cycles for SIBs), which are modify enhanced comparing with reported works. The effective strategy can provide an available approach to build self-standing and flexible architecture, which is beneficial for the design of electrode materials for SIBs.
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关键词
SnSe nanoplates,3D conductive network,Electrospinning,Self-standing,Electrochemical properties
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