Conductive Dual-Network Hydrogel-Based Multifunctional Triboelectric Nanogenerator for Temperature and Pressure Distribution Sensing

Conductive hydrogels are gaining attention in flexible electronics due to their high electrical conductivity and stretchable mechanical properties. Utilizing conductive hydrogels as electrodes in triboelectric nanogenerators (TENG) offers a promising avenue for developing versatile, flexible devices. However, the preparation of a multifunctional hydrogel-based TENG remains a challenging task. Here, a dual-network hydrogel TENG is denoted as DNH-TENG. It comprises poly(3,4-ethylenedioxythiophene): poly (styrene sulfonate) (PEDOT: PSS)/poly (vinyl alcohol) (PVA)/carboxylated multi-walled carbon nanotube (MWCNT-COOH) and offers the advantages of straightforward fabrication, versatile applications, and efficient output performance. Preparing a double network by combining a conductive network with a soft network improves the tensile properties but reduces its conductivity significantly. Further doping MWCNT-COOH with the dual-network leads to a conjugation effect and hydrogen bonding. This enhancement fortifies the hydrogel structure and augments the electrode's conductivity and mechanical properties. In single electrode mode, the DNH-TENG exhibits a short-circuit current of 16.2 μA, a transfer charge of 97.3 nC, and an open-circuit voltage of 270.5V. Furthermore, DNH-TENG exhibits an impressive stretchability, allowing it to be extended to 566%. Using DNH-TENG's exceptional stretchability and ultrahigh sensitivity to mechanical and temperature stimuli, we designed DNH-TENG-based sensor arrays to showcase temperature and pressure distribution monitoring applications.