A new quantitative method via on-line mass spectrometer: Application in biomass char/NO reaction

A novel quantitative analysis method via on-line mass spectrometer (OMS) was developed to calculate the mass flows of the reactants and products for the reaction between NO and biomass char in micro-fluidized bed. The experimental results showed that the quantitative method could accurately calculate the mass flow rate of each gas even though there were ion currents overlapping at mass-to-charge ratio (m/z) = 12,16, and 28 when CO, CO2 and N2 were simultaneously present in OMS. Furthermore, the method facilitated the quantitative analysis of gaseous reactants and products, thereby enabling the assessment of mass conversions of carbon (C) and nitrogen (N) in the NO reduction reaction. It was observed that CO was the predominant carbon-containing product in the reaction involving biomass char and NO at 900 °C, with over 96 % of nitrogen in NO participating in the reduction reaction being converted to N2. This study also revealed that increasing the fluidization number, NO concentration, and temperature in the micro-fluidized bed could significantly accelerate the conversion processes of C and N in the reduction of NO by biomass char. The peak mass flow rates of CO, CO2, and N2 were found to increase correspondingly with higher NO concentrations and temperature levels. The NO reduction process over sawdust char was compared to that of corncob char, showing a higher maximum NO reduction efficiency. The reaction order with respect to NO concentration was determined to be 0.82 for corncob char and 0.68 for sawdust char. Additionally, the apparent activation energies were determined to be 92.35 kJ/mol for corncob char and 125.60 kJ/mol for sawdust char, respectively.