Coordinating nature of M₆L₁₂ double-stranded macrocycles: co-ligand competition of perchlorate, water, and acetonitrile depending on metal(II) ions

Seonghyeon An,Jihun Han,Dongwon Kim,Haeri Lee,Ok-Sang Jung

Dalton Transactions（2024）

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摘要

Self-assembly of M(ClO4)2 (M(II) = Mn(II), Co(II), Ni(II), Cu(II), and Zn(II)) with dicyclopentyldi(pyridine-3-yl)silane (L) as a donor in the same mixture of acetonitrile and toluene produces crystals consisting of M6L12...

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Coordinating nature of M6L12 double-stranded macrocycles: co-ligand competition of perchlorate, water, and acetonitrile depending on metal(II) ions

Coordinating nature of M₆L₁₂ double-stranded macrocycles: co-ligand competition of perchlorate, water, and acetonitrile depending on metal(II) ions