Effects of partial isovalent substitution of V with (Ti,Fe) on redox reactivity in Li₂VO₂F battery cathodes

Moritz Hirsbrunner,Ida Källquist,Jolla Kullgren,Hakan Rensmo,Maria Hahlin,Laurent Duda

Journal of Materials Chemistry A（2024）

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摘要

We applied photon-only x-ray absorption spectroscopy and resonant inelastic x-ray scattering to study the bulk properties of Li-rich disordered rock salt oxyfluoride cathodes Li2VO2F, Li2V0.5Ti0.5O2F and Li2V0.5Fe0.5O2F. We have systematically...

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Effects of partial isovalent substitution of V with (Ti,Fe) on redox reactivity in Li2VO2F battery cathodes

Effects of partial isovalent substitution of V with (Ti,Fe) on redox reactivity in Li₂VO₂F battery cathodes