Enantioselective de novo synthesis of 14-hydroxy-6-oxomorphinans.

Jonathan C Moore, Louis Modell, Jacqueline R Glenn,Kieran D Jones,Stephen P Argent,J Robert Lane,Meritxell Canals, Hon Wai Lam

Chemical communications (Cambridge, England)（2024）

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摘要

The enantioselective de novo synthesis of pharmacologically important 14-hydroxy-6-oxomorphinans is described. 4,5-Desoxynaltrexone and 4,5-desoxynaloxone were prepared using this route and their biological activities against the opioid receptors were measured.

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