2-Benzoyl-4-phenyl-1,2,5-thiadiazol-3(2H)-one 1,1-Dioxide

Emmanouil Broumidis,Samuel B. H. Patterson,Georgina M. Rosair,Panayiotis A. Koutentis,Andreas S. Kalogirou

MOLBANK（2024）

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摘要

3,5-Diphenyl-4H-1,2,6-thiadiazin-4-one treated with meta-chloroperoxybenzoic acid undergoes an oxidative ring contraction to give 2-benzoyl-4-phenyl-1,2,5-thiadiazol-3(2H)-one 1,1-dioxide in a 29% yield, the structure of which is supported by single-crystal X-ray diffraction analysis and the available spectroscopic data.

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关键词

heterocycle,thiadiazine,thiadiazole,ring contraction,sulfone,oxidation

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