Polyamide Thin-Film Composite Membranes with Enhanced Interfacial Stability for Durable Organic Solvent Nanofiltration

Polyamide thin-film composite (TFC) membranes present a promising option for organic solvent nanofiltration (OSN) due to their superior advantages in facile fabrication and high separation efficiency. However, existing TFC-based OSN membranes are heavily limited by their weak interfacial stability in organic solvents, because many solvent-resistant porous supports are hydrophobic and have poor interfacial compatibility to polyamide. Herein, we report a polyamide TFC membrane with enhanced interfacial stability and durable OSN performance, by multifunctional surface modification and in-situ interfacial polymerization on a hydrophobic and solvent-resistant polypropylene substrate. Distinct from nascent ones, the polypropylene substrates modified by tannic acid/aminopropyltriethoxysilane coating possess excellent hydrophilicity and more functional groups, in which the former allows for the in-situ synthesis of integral polyamide layers via interfacial polymerization and the latter greatly enhances the binding strength between the polyamide layer and PP substrate by 30 times. With this method, the TFC membranes exhibit excellent thermal stability in 80 °C dimethylformamide solution. Meanwhile, the TFC membranes display high ethanol permeance (9.2 L m-2 h-1 bar-1) and acid fuchsin rejection (98.5%), outperforming the performance of most OSN membranes reported. This straightforward method, robust structural stability, and extraordinary performance make the TFC membranes a step closer to commercial OSN membranes.