Influence of Strong -Acceptor Ligands on Cr-K-edge X-Ray Absorption Spectral Signatures and Consequences on Interpretation of Surface Sites in the Phillips Catalyst

Yuya Kakiuchi,Svetlana Shapovalova,Bogdan Olegovich Protsenko,Sergey Guda,O. V. Safonova,Alexander A. Guda,Christophe Coperet

Catalysis Science & Technology（2024）

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摘要

X-ray absorption spectroscopy (XAS) has been central to study the Phillips polymerization catalyst (CrO3/SiO2). As the Cr K-edge XAS signatures are sensitive to both oxidation state, geometry and types of...

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