Effects of reaction pH on regular nanorods and hierarchically structured β-Ga2O3 and their isopropanol sensing capabilities

Nyepudzai C. Gatsi,Gugu H. Mhlongo,Nosipho Moloto,Rudolph M. Erasmus, Odireleng M. Ntwaeaborwa

Materialia(2024)

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摘要
Real-time detection of isopropanol is important for indoor air quality monitoring to improve human health. In this study, regular and hierarchical nanorod-based β−Ga2O3 morphological features were prepared using the microwave-assisted hydrothermal method following the variation of the reaction pH levels. A systematic study on their gas sensing performances was conducted to evaluate their potential as isopropanol gas sensing platforms. The sensor response and response times were directly controlled by morphology of β−Ga2O3. The randomly oriented β−Ga2O3 nanorods presented the highest response of 6.7 towards 90 ppm isopropanol while the β−Ga2O3 nanodandelions showed the fastest response/recovery times of 47/25 s. The observed variation in the gas sensing performances of the different β−Ga2O3 structures can be attributed to changes in morphological, textural, and compositional properties induced by the controlled reaction pH levels.
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关键词
Gallium oxide,isopropanol,gas sensing,nanorods,nanobundles,nanodandelions
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