Halogen-Bond-Promoted Direct Cross-Coupling of Ethyl 3-bromo-3-alkyl-2,2-difluoropropanoate with Coumarins/Quinolinones

Guoliang Pu, Shi-Yuan Song,Jian Yang,Peng Guo,Jia Jia,Peijun Liu,Xuefei Li,Ping Liu,Chun-Yang He

Organic Chemistry Frontiers（2024）

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摘要

Herein, we developed a practical method for the direct cross-coupling of ethyl 3-bromo-3-alkyl-2,2-difluoropropanoate with coumarins/quinolinones, leveraging a halogen bond as the pivotal non-covalent interaction. Employing this protocol, a library of...

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