TEMPO/O2 Synergistically Mediated BiBrO‐Photocatalyzed Decarboxylative Phosphorylation of N‐Arylglycines

With both TEMPO and O2 (in air) as the homogeneous redox mediators, BiBrO as the heterogeneous semiconductor photocatalyst, the first example of semi‐heterogeneous photocatalytic decarboxylative phosphorylation of N‐arylglycines with diarylphosphine oxides was established. A series of α‐amino phosphinoxides were efficiently synthesized