Structural and Electrochemical Performance of Sr_0.9La_0.1WO₄ Electrolyte Materials for Solid Oxide Fuel Cells

Abstract A possible component of power generation technologies, solid oxide fuel cells (SOFCs) offer a high fuel-to-power conversion efficiency and no negative environmental impact. The solid-state sintering process was used to synthesize the scheelite-structured Sr0.9La0.1WO4 (SLW1) electrolyte material, and phase stability and ionic conductivity were evaluated for their technological applicability for SOFC applications. The resulting mixture, which was a single phase in a tetragonal crystal system, produced a scheelite structure of the space group I41/a. Its symmetry, space group, and structural characteristics are confirmed by X-ray diffraction (XRD) at room temperature and the Rietveld analysis that follows. A highly dense crystal structure was revealed by SEM examination. The ionic conductivity of the SLW1 sample is higher than SBW materials and lower than the conventional BCZY perovskite structure. At 900°C in both the wet Ar and dry Ar conditions, the SLW1 sample’s ionic conductivity was 2.41 × 10−5 S cm-1 and 1.76 × 10−5 Scm−1. This scheelite-like compound showed a thick microstructure and substantial conductivity, making it a potential mixed ion-conducting electrolyte for SOFC.