La doping greatly enhances electrochemical alkaline seawater oxidation over Ni(OH)2 nanosheet

Wenjing Tang, Jie Zou, Zixiao Li, Xuefeng Zhang,Ting Xie, Jun Li,Xun He, Xiaolan Tang, Xuwei Liu, Wei Chu,Asmaa Farouk,Mohamed S. Hamdy, Yingchun Yang, Wenchuang (Walter) Hu,Xuping Sun

CATALYSIS SCIENCE & TECHNOLOGY(2024)

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摘要
The utilization of seawater electrolysis is recognized as a promising method for generating H-2 as a substitute for conventional technology. Nevertheless, it is impeded by anode catalysts with restricted lifespans, primarily due to chloride-induced competitive chemical reactions. This study reports an La-doped Ni(OH)(2) nanosheet supported on Ni foam (La-Ni(OH)(2)/NF) as an outstanding oxygen evolution reaction electrocatalyst, which demonstrates remarkable performance in alkaline seawater. Impressively, the achievement of a high current density (500 mA cm(-2)) requires a low overpotential of only 434 mV, surpassing that of Ni(OH)(2)/NF (532 mV). In addition, La-Ni(OH)(2)/NF exhibits outstanding electrochemical stability for the duration of more than 200 h in alkaline seawater.
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