Preparation of Three Component PVDF‐Bi₄V₂O₁₁‐SDS Composites with Enhanced Dielectric and Electrical Properties

AbstractIn this work, poly(vinylidene fluoride) (PVDF)‐bismuth vanadate (Bi4V2O11; BVO)‐sodium dodecyl sulfate (SDS) composite films are fabricated by the solution casting method. The frequency dependence of the dielectric and electric performances of the resultant PVDF‐BVO‐SDS composites on various weight percentages of SDS contents is investigated. The results demonstrate that the three‐component PVDF‐BVO‐SDS composites have a superior dielectric constant (96) and suppressed dielectric loss (<1) at 102 Hz for 20 wt% of SDS contents. The surface morphology of the PVDF‐BVO‐SDS composites shows that SDS is successfully reinforced on the PVDF‐BVO matrix with better homogeneity. The ac conductivity of the PVDF‐BVO‐SDS composites is also improved, which is helpful for the enhancement of the dielectric constant and relatively low loss in the composites. Moreover, the PVDF‐BVO‐SDS composite also exhibits a larger value of the dielectric constant (96) than the pristine PVDF matrix, which is 15 times higher than that of the pristine one. These significantly enhanced dielectric and electrical characteristics of PVDF‐BVO‐SDS composites will fulfill the practical criteria for their use in high dielectric‐constant capacitors and energy storage devices.