Copper-Catalyzed Asymmetric Friedel-Crafts Hydroxyalkylation of Pyrazole-4,5-diones with 5-Aminoisoxazoles

Siyu Gao,Xiang Sun, Sijie Peng,Zhenggen Zha,Qi Sun,Zhiyong Wang

Organic & Biomolecular Chemistry（2024）

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摘要

An asymmetric Friedel-Crafts hydroxyalkylation reaction of 5-aminoisoxazoles with pyrazole-4,5-diones was developed under the catalysis of 5% chiral copper complexes. This reaction exhibits a functional group tolerance and excellent enantioselectivity. Moreover,...

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