Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions

Kazuki Nakamura,Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi

Inorganic Chemistry Frontiers（2024）

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摘要

A newly synthesized photomagnet based on a cyanido-bridged Co–W assembly, [{Co(isoquinoline)4}3{W(CN)8}2]·2EtOH (CoWisoq), exhibits a controllable photoinduced (PI) phase with a metamagnetic behavior. The PI phase shows a transition from paramagnetic...

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