Facile synthesis of hydroquinone linked 3,3’‐steroid dimers via a modified Mitsunobu protocol

Patryk Klochowicz, Jacek W. Morzycki, Claudia M. Ramírez-Lozano,Rosa Santillan,Dorota Czajkowska-Szczykowska

European Journal of Organic Chemistry（2024）

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摘要

A successful approach for the construction of steroid dimers with a hydroquinone linker under PBu3/TMAD/Et3N/toluene conditions is described. This study provided a new one‐step methodology for the design and synthesis of bis‐steroidal 1,4‐phenylene diethers using mild and effective reagents.

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关键词

hydroquinone,Mitsunobu reaction,steroids,steroid dimers

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