Green- and Blue-Emitting Tb3+-Activated Linde Type A Zeolite-Derived Boro-Aluminosilicate Glass for Deep UV Detection/Imaging.

Yongneng Xiao,Shaoyi Hou,Zhenhuai Yang, Xingxing Huang, Yuanjun Guo, Siyu Ji, Xiaochan Huang, Fengshuang Wang,Qiang Hu, Xiaodong Guo

Materials (Basel, Switzerland)(2024)

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摘要
Tb3+-activated LTA zeolite-derived boro-aluminosilicate glass samples with a composition of xTb2O3-68(Na2O-Al2O3-SiO2)-32B2O3 (x = 0.2, 1.0 and 10 extra wt%) were prepared using the melt-quenching method. The emission spectra recorded upon ultraviolet (UV) excitation with two different wavelengths of 193 and 378 nm showed blue light (5D3 to 7FJ=6,5,4 and 5D4 to 7F6 transitions of Tb3+) and green light (5D4 to 7F5 transition of Tb3+) emissions with comparable intensities up to a Tb3+ concentration of 10 extra wt%. Of note, the mean decay times of the green luminescence of the glass samples were relatively fast (<20 μs). The synthesized glass has potential in applications concerning UV imaging, UV detection, and plasma display panels.
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