Effects of coal gangue on the ash initial deformation temperature and gasification characteristic of biomass

The effects of coal gangue (CG) on the ash initial deformation temperature (IDT) and CO2 gasification characteristic of biomass (chestnut shell [CS] and soybean straw [SS]) were investigated by ash fusion tester and thermogravimetric analyzer, respectively. The IDTs of CS and SS ashes were low because of the presence of abundant low melting point (MP) airchildite (K2Ca(CO3)2) and arcanite (K2SO4), and they were efficiently improved by the CG additions of 2%-10% mass ratios. The increases in the IDTs of CS and SS ashes were resulted from the conversions of fairchildite and arcanite into high MP K-Al silicates (kalsilite [KAlSiO4], leucite [KAlSi2O6], etc.). The gasification reactivities of CS/CG mixtures stayed below that of CS, and they decreased with increasing CG mass ratios (4%-10%) and increased with increasing temperatures (900-1000 degrees C). At 900 degrees C, CG addition caused a decrease in the gasification reactivity of SS. When the temperature reached 950 degrees C, the CG addition of 4% mass ratio increased the gasification reactivity of SS instead. The synergistic effect between biomass and CG during cogasification was more significant at low CG mass ratio and high temperature, and the synergistic effect between SS and CG was more intense than that between CS and CG.