Bamboo fiber reinforced poly (acrylonitrile-styrene-acrylic)/chlorinated polyethylene via compabilization

In the quest to enhance the performance of natural fiber-reinforced polymer composites, achieving optimal dispersion of fiber materials within a polymeric matrix has been identified as a key strategy. Traditional approaches, such as the surface modification of natural fibers, often necessitate the use of additional synthetic chemical processes, presenting a significant challenge. In this work, taking poly (acrylonitrile–styrene–acrylic) (ASA) and bamboo fiber (BF) as a model system, we attempt to use the elastomer-chlorinated polyethylene (CPE) as a compatibilizer to tailor the mechanical properties of ASA/CPE/BF ternary composites. It was found that increasing CPE content contributed to more remarkable reinforcing efficiency, where composite with 15 phr CPE exhibited a nearly four-fold increase in reinforcing efficiency of tensile strength (20 %) compared with that of composite system without CPE (4.1 %). Such improvement was ascribed to the compatibilizing effect exerted by CPE, which prevented the aggregation of BF within polymeric matrix. Surface properties suggested the stronger interface between CPE and BF compared to that between ASA and BF and thereby contributed to the compabilizing effect. Since no chemical process was involved, it is suggested that the introduction of elastomer to be a universal, green and sustainable approach to achieve the reinforcement.