Efficient synthesis of ethanol and propanediol from glucose via a noble metal promoted CuWO4 catalyst
Applied Catalysis A: General(2024)
摘要
Biomass is the most promising carbon feedstock for producing chemicals and fuels as substitutes for fossil resources. In this work, hydrogenolysis of glucose to ethanol (EtOH) and 1,3-propanediol (1,3-PDO) were carried out over multi-function noble metal promoted CuWO4 (0.1wt.% Ru, Pt and Pd) catalysts using a continuous-flow fixed-bed reactor. Amazingly, the Ru/CuWO4 catalyst presented the best catalytic performance with 84.3% glucose conversion, 63.2% EtOH and 21.2% 1,3-PDO selectivities over 40h reaction. An array of characterization techniques, including XPS, Cu LMM AES, in-situ CO-DRIFTS, NH3-TPD, Py-FTIR, and operando EG-DRIFTS, were applied to reveal the nature of converting glucose into EtOH and 1,3-PDO. It is discovered that the added small amount of Ru tuned the chemical states of W and Cu, resulting in forming the highest content of W5+ and Cu0 on the Ru-promoted catalyst, which improves the glucose hydrogenolysis to EtOH. Besides, the strong Brønsted acid sites (BASs) derived from W6+ contribute to relatively high 1,3-PDO selectivity on Pt/CuWO4 catalyst.
更多查看译文
关键词
Glucose,Hydrogenolysis,Ethanol,Ruthenium,CuWO4
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要