Mechanical effects of carboxymethylcellulose binder in hard carbon electrodes

Electrodes in sodium-ion batteries endure mechanical stress during production and application, which can damage these fragile coatings, causing performance inefficiencies and early failure. Binder material provides elasticity in electrode composites to resist fracture, but evaluating the effectiveness of binder is complicated by substrate dependency of these films, while conventional cell tests are beset by multiple electrochemical variables. This work introduces a practical low-cost indentation test to determine the elasticity of hard carbon electrodes containing standard carboxymethylcellulose binder. Using the proposed method, relative elastic moduli of hard carbon electrodes were found to be 0.079 GPa (1 GPa (3 computational model of film deflection to predict mechanical deformation under stress. Effects on the electrochemical performance of hard carbon anodes were also demonstrated with impedance spectroscopy and galvanostatic cycling of sodium half-cells, revealing 8-9 binder compared with those containing 1 content in hard carbon electrodes should be selected according to requirements for both cycle life and film flexibility during cell manufacturing.