Direct Growth of a Polymer Film to Induce Horizontal Orientation of Zn4(OH)6SO4·xH2O for Stable Zn Metal Batteries.

The loose and randomly oriented byproduct (i.e., Zn4(OH)6SO4·xH2O, ZHS) in situ formed on the zinc (Zn) surface is recognized to be the primary cause for dendritic Zn growth and side reactions. Switching the detrimental passivation film into a dense and kinetically favorable solid electrolyte interphase (SEI) is a straightforward strategy to tackle these issues faced by Zn metal anodes but remains largely unexplored. Herein, a new polymer film directly grown on Zn metal through room-temperature plasma-enhanced chemical vapor deposition is proposed to induce the lateral growth of ZHS nanosheets and decrease the Zn2+ desolvation barrier, thereby forming a beneficial composite SEI for suppressing Zn dendrite growth and surface corrosion. As a result of the joint effect, we realize an impressively stable cycling behavior in symmetric cell over 3400 h at 2 mA cm-2. Moreover, full cells also demonstrate prolonged lifespans. This work opens a new avenue for stabilizing Zn metal batteries by turning detrimental ZHS into a favorable interlayer.