Oxygen Storage Capacity of Y0.8Ca0.2BaCo4 – xMxO7 + δ (M = Fe, Ga, Al; 0 < x < 1) Solid Solutions during Thermal Cycling in Air

D. I. Turkin, K. S. Tolstov, M. V. Yurchenko,A. Yu. Suntsov,V. L. Kozhevnikov

Inorganic Materials（2024）

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摘要

We have studied the behavior of Y1 – yCayBaCo4 – xMxO7 + δ solid solutions in cyclic oxygen absorption/release processes in air at temperatures in the range 350–580°C. Y0.8Ca0.2BaCoO7 + δ has been found to absorb the largest amount of oxygen: 0.52 wt

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关键词

nonstoichiometric oxides,oxygen exchange,thermal cycling

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