Insights into the genesis and geological significance of iron-manganese precipitates in the Baltic Sea, Gulf of Finland seafloor

This study investigates the distribution and geological implications of iron-manganese (Fe-Mn) oxyhydroxide precipitates on the seafloor of the Gulf of Finland, with a particular focus on associated pockmarks and Fe-Mn concretions. The formations occur in regions devoid of modern sediment deposition, revealing exposure of late glacial glacio-lacustrine varved clays, glacial tills, or bedrock. Pockmarks, up to 3 m deep and 30-60 m wide, coexist with Fe-Mn concretions, exhibiting sub-vertical walls and microbial colonies, suggesting active seepage of chemically reduced fluids from underlying strata. Globally occurring Fe-Mn concretions, sedimentary bodies primarily composed of iron and manganese compounds, exhibiting round or crust-like shapes formed through redox-driven processes in seabed environments. Microbial activity accelerates necessary redox reactions, influencing the growth of these concretions. The study delves into the morphological, chemical, and mineralogical characteristics of Fe-Mn concretions in the Gulf of Finland, identifying two distinct types—concentric and crust-like—with varied compositions, hinting at diverse formation mechanisms. Elevated concentrations of precious and rare earth metals in these concretions raise interest for potential industrial applications. Fe-Mn concretions also serve as valuable indicators of sedimentary processes' geological history, exposing environmental changes over time, including anthropogenic pollution. Despite advancements, the genetic types of Fe-Mn concretions in Estonian sea areas remain elusive, emphasizing the need for further research. The study integrates findings from three recent international expeditions to the central Gulf of Finland, aiming to comprehensively understand the relationships between fluid seepage, Fe-Mn concretions, and seafloor features. These expeditions collect representative materials, focusing on the timing and controls of groundwater discharge, mineral precipitation, and associated seafloor microbial processes. The preliminary results provide insights into the intricate geological processes underlying the observed seafloor features. In conclusion, this collaborative effort contributes valuable information about the distribution and genetic characteristics of Fe-Mn precipitates and associated features in the Gulf of Finland. The simultaneous investigation of pockmarks and Fe-Mn concretions, along with their geological implications, enhances our understanding of these complex marine environments. Further research is essential to unravel the exact genetic types of Fe-Mn concretions in Estonian sea areas and to refine our knowledge of the dynamic interactions between fluid seepage, mineral precipitation, and microbial processes on the seafloor.