Study of a New Hydrogen Sensor Based on the Synthesis of a Sputtered In-Sn-Zn-O Thin Film and Evaporated Palladium Nanoparticles

Pao-Chi Yao, Chi-Kang Kuo, Jung-Chuan Wang, Pai-Yi Chu,Wei-Chou Hsu,Wen-Chau Liu

IEEE TRANSACTIONS ON ELECTRON DEVICES(2024)

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摘要
A new and interesting hydrogen (H-2) gas sensor based on an In-Sn-Zn-O (ITZO) thin film modified with palladium nanoparticles (Pd NPs) on a sapphire (Al2O3) substrate is manufactured and investigated herein. High-resolution scanning electron microscopy (HRSEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) are employed to study intrinsic material properties. Experimentally, under 1% H-2/air gas, the fabricated Pd NP/ITZO sensor exhibits prominent sensing performance, including a higher sensing response S-R of 12 890 with a response (recovery) time of 106 s (13 s), and a lower detectable content of 1 ppm H-2/air at 225(degrees)C is obtained. Moreover, the sensor shows high reproducibility, excellent selectivity, and long-term stability (91 days) toward H-2 gas.
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关键词
Temperature measurement,Zinc,Transmission electron microscopy,Hydrogen sensor,In-Sn-Zn-O (ITZO),long-term stability,palladium nanoparticles (Pd NPs),repeatability,selectivity
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